chemical shift

in photoelectron and Auger spectra
The displacement of photoelectron or Auger peak energies originating from changes in electron binding energies as a consequence of differences in the chemical environment of the atoms.
PAC, 1979, 51, 2243. (General aspects of trace analytical methods—IV. Recommendations for nomenclature, standard procedures and reporting of experimental data for surface analysis techniques) on page 2247 [Terms] [Paper]